Material Safety Data Sheet


1. Chemical Product and Company Identification

 
     DESCRIPTION:     KRAZY GLUE ALL PURPOSE
     PRODUCT TYPE:    CYANOACRYLATE ADHESIVE
     APPLICATION:     KG-583, KG-585, KG-517

�         Manufacturer/Supplier Information

 
     MSDS Prepared by:
     Elmer's Products, Inc.                           Emergency Phone Number
     1 Easton Oval                                    Poison Control Center
     Columbus, OH  43219                              888-516-2502
     For additional health, safety or regulatory information, call 888-435-6377
     Call 1-800-848-9400 to place an order or request additional MSDSs.

2. Composition, Information on Ingredients

 
     The ingredients listed below have been associated with one or more
     immediate and/or delayed(*) health hazards.  Risk of damage and effects
     depends upon duration and level of exposure.  BEFORE USING, HANDLING, OR
     EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.
                                                                     % by weight
       7085-85-0 Ethyl 2-Cyanoacrylate 

3. Hazards Identification

 

3.1 Emergency Overview

 
     Appearance                          Colorless liquid
     Odor                                Irritating
     CAUTION!
     COMBUSTIBLE
     May become unstable at high temperatures or may react with water.
     May be harmful if inhaled.  May cause irritation of nose, throat and
     lungs.
     Bonds skin instantly.  Causes skin irritation.
     Bonds eyelids instantly.  Causes eye irritation.

�         HMIS Rating

 
           HEALTH = 2 (moderate)
     FLAMMABILITY = 2 (moderate)
       REACTIVITY = 1 (slight)

3.2 Potential Health Effects

 

�         Immediate Hazards

 
     INGESTION:   No hazards known to company.
     INHALATION:  May be harmful if inhaled.  Liquid or vapor may cause
                  irritation of nose, throat and lungs.
     SKIN:        Bonds skin instantly.  Causes irritation.
     EYES:        Bonds eyelids instantly.  Causes irritation.

�         Delayed Hazards

 
     None of the components present in this product at concentrations equal
     to or greater than 0.1% have been listed by NTP, classified by IARC,
     nor regulated by OSHA as a carcinogen.

4. First Aid Measures

 
     INGESTION:   If accidentally swallowed, dilute by drinking large
                  quantities of water.  Immediately contact poison control
                  center or hospital emergency room for any other
                  additional treatment directions.
     INHALATION:  If inhaled, remove to fresh air.  If not breathing,
                  give artificial respiration, preferably mouth-to-mouth.
                  Call a physician.
     SKIN:        If skin bonding occurs, soak in nail polish remover
                  or acetone and carefully peel or roll skin apart (do not
                  pull).
     EYES:        If eye contact occurs, hold eyelid open and rinse
                  thoroughly but gently with only water for 15 minutes and
                  GET MEDICAL ATTENTION.  Do not use any solvents to
                  flush the eye and its surroundings.  Liquid glue will
                  sting eye temporarily.  Solidified glue may irritate eye
                  like a grain of sand and should be treated by an eye
                  doctor.

5. Fire Fighting Measures

 
     Autoignition Temperature            485 deg C
     Upper/Lower Flammable Limits        Not available
     Up/Lower Explosive Limits, % by Vol Not available
     Flash Point                         83 deg C (CC)
     COMBUSTIBLE.
     Keep away from heat and flame.
     In case of fire, use water spray, dry chemical, foam or CO2.  Use
     water to keep fire-exposed containers cool.

6. Accidental Release Measures

 
     Eliminate all ignition sources.  Soak up with absorbent material and
     remove to a chemical disposal area.  Prevent entry into natural bodies
     of water.

7. Handling and Storage

 

7.1 Handling

 
     Handle in accordance with good industrial hygiene and safety
     practices.  These practices include avoiding unnecessary exposure and
     removal of the material from eyes, skin and clothing.
     Wash thoroughly after handling.  Always use appropriate Personal
     Protective Equipment (PPE).
     INHALATION:  Avoid breathing vapor.  Use with adequate
                  ventilation.
     SKIN:  Avoid contact with skin and clothing.
     EYES:  Avoid contact with eyes.

7.2 Storage

 
     Keep away from amines.
     Store in cool, dry area away from sun and heat.
     Keep containers tightly closed.
     Exposure to small amounts of moisture, even moisture in air, causes
     polymerization and renders the product unusable.
     Keep away from heat, sparks, flame and other ignition sources.

8. Exposure Controls/Personal Protection

 

8.1 Exposure Controls

 
     ENGINEERING CONTROLS:  The following exposure control techniques may
     be used to effectively minimize employee exposure: local exhaust
     ventilation, enclosed system design, process isolation and remote
     control in combination with appropriate use of personal protective
     equipment and prudent work practices.  These techniques may not
     necessarily address all issues pertaining to your operations.  We,
     therefore, recommend that you consult with experts of your choice to
     determine whether or not your programs are adequate.
     If airborne contaminants are generated when the material is heated or
     handled, sufficient ventilation in volume and air flow patterns should
     be provided to keep air contaminant concentration levels below
     acceptable criteria.

8.2 Personal Protection

 
     Use goggles if contact is likely.  Wear impervious gloves as required
     to prevent skin contact.

8.3 Exposure Guidelines

 
     Ethyl 2-Cyanoacrylate      7085-85-0     
     ACGIH TLV: 0.2 ppm (1 mg/m³) TWA
     OSHA PEL: NONE ESTABLISHED

9. Physical and Chemical Properties

 
     Percent Volatiles                   Not determined
     pH @ 25 C                           Not available
     Specific Gravity                    1.05
     Appearance                          Colorless liquid
     Autoignition Temperature            485 deg C
     Boiling Point                       62 deg C (5 mm Hg)
     Vapor Density (Air=1)               > 1
     Vapor Pressure, mm Hg @ 20 C        0.13 (@ 20 deg C)
     Evaporation Rate (Butyl Acetate=1)  < 1
     Upper/Lower Flammable Limits        Not available
     Up/Lower Explosive Limits, % by Vol Not available
     Flash Point                         83 deg C (CC)
     Freezing Point                      < -20 deg C
     Odor                                Irritating
     Odor Threshold, ppm                 Not available
     Solubility in Water                 Negligible
     Coefficient of Water/Oil Distrib.   Not applicable

10. Stability and Reactivity

 
     Normally stable, but may become unstable at high temperatures or may
     react with water.

·         Conditions to Avoid:

 
     Exposure to heat, flame and incompatibles.

·         Incompatibilities:

 
     Water, alcohols, amines, bases and direct UV.

·         Decomposition products may include:

 
     Oxides of carbon.

·         Hazardous polymerization:

 
     Will not occur.

·         Other Hazards:

 
     None known to company.

11. Toxicological Information

 
     See Section 3 Hazards Identification information.
     Ethyl 2-Cyanoacrylate      7085-85-0     
     LC50: Not available
     LD50: Not available

12. Ecological Information

 
     Not determined.

13. Disposal Considerations

 
     Recover free liquid.  Absorb residue and dispose of according to
     local, state/provincial, and federal requirements.
     Empty container:  May contain explosive vapors.  DO NOT cut, puncture
     or weld on or nearby.

14. Transport Information

 

14.1 U.S. Department of Transportation (DOT)

 
     The data provided in this section is for information only and may not
     be specific to your package size.  You will need to apply the
     appropriate regulations to properly classify your shipment for
     transportation.
     Non-Regulated.

14.2 Canadian Transportation of Dangerous Goods (TDG)

 
     Non-Regulated.

15. Regulatory Information (Selected Regulations)

 

15.1 U.S. Federal Regulations

 

·         OSHA Hazard Communication Standard 29CFR1910.1200

 
     This material is a "health hazard" and/or a "physical hazard" as
     determined when reviewed according to the requirements of the
     Occupational Safety and Health Administration 29 CFR Part 1910.1200
     "Hazard Communication" Standard.

·         SARA Title III: Section 311/312

 
     Fire hazard
     Immediate health hazard

·         SARA Title III Section 313 and 40 CFR Part 372

 
     This product contains the following toxic chemical(s) subject to the
     reporting requirements of Section 313 of Title III of the Superfund
     Amendments and Reauthorization Act of 1986, and Subpart C-Supplier
     Notification Requirement of 40 CFR Part 372.
     None required per SARA TITLE III SECTION 313.

·         TSCA Section 8(b) Inventory

 
     All reportable chemical substances are listed on the TSCA Inventory.
     We rely on certifications of compliance from our suppliers for
     chemical substances not manufactured by us.

15.2 Canadian Regulations

 

·         Workplace Hazardous Materials Information System (WHMIS)

 
     This product has been classified in accordance with the hazard
     criteria of the Controlled Products Regulation (CPR) and the MSDS
     contains all the information required by the CPR.
          CLASS D, DIV 2B          
          CLASS B, DIV 3           

·         Canadian Environmental Protection Act (CEPA)

 
     All reportable chemical substances are listed on the Domestic
     Substances List (DSL) or otherwise comply with CEPA new substance
     notification requirements.

·         National Pollutant Release Inventory (NPRI)

 
     This product contains the following chemical(s) subject to the
     reporting requirements of the Canadian Environmental Protection Act
     (CEPA) subsection 16(1), National Pollutant Release Inventory.
     None required.

16. Other Information

 
     CL (Cautionary Labeling): Products bearing the CL (Cautionary
     Labeling) Seal of The Art & Creative Materials Institute, Inc. (ACMI)
     are certified to be properly labeled in a program of toxicological
     evaluation by a medical expert. This program is reviewed by ACMI's
     Toxicological Advisory Board. These products are certified by ACMI
     to be labeled in accordance with the chronic hazard labeling
     standard, ASTM D-4236 and Federal Law, P.L. 100-695.

·         User's Responsibility

 
     The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
     Hazardous Materials Information System (WHMIS) require that the information
     contained on these sheets be made available to your workers.  Educate and
     train your workers regarding OSHA and WHMIS precautions.  Instruct your
     workers to handle this product properly.  Consult with appropriate experts
     to guard against hazards associated with use of this product and its
     ingredients.

·         Disclaimer

 
     SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
     MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
     shall conform to contracted specifications, and that the product does not
     infringe any valid United States or Canadian patent.  No claim of any kind
     shall be greater in amount than the purchase price of the quantity of
     product in respect of which damages are claimed.  In no event shall Seller
     be liable for incidental or consequential damages, whether Buyer's claim is
     based on contract, breach of warranty, negligence or otherwise.

 
                                                  CURRENT ISSUE: 09-OCT-06
                                                 PREVIOUS ISSUE: 13-JAN-05